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Tris(ethylenediamine)nickel perchlorate is a coordination complex with ethylenediamine to nickel ions. It is easy to prepare and is highly energetic, deflagarating easily in a flame.

PropertiesEdit

ChemicalEdit

Tris(ethylenediamine)nickel perchlorate is highly explosive, though its oxygen balance is not optimal, with excess ethylenediamine in the structure. Although it is energetic, it can be stored indefinitely. It is poorly soluble in water, and this can be used to aid in its production.

PhysicalEdit

Unlike its nickel perchlorate precursor, tris(ethylenediamine)nickel perchlorate has a strongly purple hue.

PreparationEdit

Tris(ethylenediamine)nickel perchlorate can be prepared by dissolving nickel(II) oxide, hydroxide, or carbonate in perchloric acid and then adding ethylenediamine until the solution turns purple. After a day it will precipitate and the crystals can be collected.

SafetyEdit

Keep away from open flames.

See alsoEdit

ReferencesEdit


http://woelen.homescience.net/science/chem/exps/Ni_en_complexes/index.html

Relevant Sciencemadness threadsEdit

Interesting and colorful coordination chemistry with ethylene diamine

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