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Acetaldehyde lewis

Acetaldehyde is the organic compound with chemical formula CH3CHO. It is the second-simplest aldehyde and finds use as a building block in organic synthesis.

PropertiesEdit

ChemicalEdit

Depending on reaction conditions, the oxidation of acetaldehyde by oxygen variously co-produces acetic anhydride and acetic acid via the intermediate peracetic acid. The process relies on a catalyst containing metal ions and is typically conducted by introduction of gaseous oxygen into liquid acetaldehyde.

PhysicalEdit

Acetaldehyde is a transparent, volatile, and extremely flammable liquid at room temperature that boils at only 20.2°C (68.4°F), making it difficult to store. The characteristic odor of acetaldehyde is sweet and reminiscent of green apple. Acetaldehyde has a flash point of only −39°C, making it absolutely crucial that any significant amount is kept away from possible ignition sources.

AvailabilityEdit

No over-the-counter source of acetaldehyde is known, and sources are unlikely due to the difficulty and danger of prolonged storage.

PreparationEdit

Industrially, acetaldehyde is produced via the oxidation of ethene over a copper-palladium catalyst. Two routes exist from ethanol, the first an exothermic, self-sustaining oxidation reaction using a copper or silver catalyst at a temperature of 500-650°C:

2CH3CH2OH + O2 → 2CH3CHO + 2H2O

The second method of preparing acetaldehyde from ethanol involves its dehydrogenation at a temperature of of 260-290 °C, again over a catalyst of copper. This route is endothermic, requiring constant and uniform heating, but has the advantage of not requiring oxygen input, which also reduces the risk of fire.

CH3CH2OH → CH3CHO + H2[1]

ProjectsEdit

HandlingEdit

SafetyEdit

Acetaldehyde is designated a probable carcinogen and is many times more toxic than ethanol, which it is a metabolite of. With a high chance of vaporization and a flash point of only −39 °C, acetaldehyde represents a significant fire hazard, and care should be made that all potential sources of ignition are kept away.

StorageEdit

Acetaldehyde must be stored in a highly temperature-controlled environment given its low boiling point, and should also be kept in a separate cabinet or secondary container in a well-ventilated space, always away from potential sources of ignition.

DisposalEdit

Acetaldehyde can be safely burned.

ReferencesEdit

  1. Ullmann's Encyclopedia Of Industrial Chemistry, Wiley-VCH (2007)

Relevant Sciencemadness threadsEdit

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